Product ID:CPE133507, POOL CLEAR JUMBO TABLETS
MSDS Date:01/23/1991
FSC:6850
NIIN:00N022345
MSDS Number: BNNPD

OLIN CORP CHEMICALS GROUP

120 LONG RIDGE RD
STAMFORD, CT 06904
US

Emergency Phone: 203-356-3449,CHEMTREC 800-242-9300

Info Phone: 203-356-3449

Cage: 53084

OLIN CORP CHEMICALS GROUP

STAMFORD, CT 06904 US

Telephone: 203-356-3449,CHEMTREC 800-242-9300

Cage: 53084

TREATMENT. EPA HAZARDOUS WASTE NO. D001.

RTECS: 9999999ZZ

BUTYL RUBBER/SARANEX TYPE GLOVES.

RTECS: 9999999ZZ

CLEAN UP ALL SPILL MATERIAL W/CLEAN, DRY

RTECS: 9999999ZZ

S-TRIAZINE, 2,4,6(1H,3H,5H)-TRIONE,1,3,5-TRICHLORO-;

CAS: 87-90-1

RTECS: XZ1925000

Fraction By Weight: 96-100%

S-TRIAZINE, 2,4,6(1H,3H,5H)-TRIONE,1,3-DICHLORO-;

CAS: 2782-57-2

RTECS: XZ1845000

Fraction By Weight: 0-4%

BLEEDING &/OR TISSUE ULCERATION.

RTECS: 9999999ZZ

ADMIN O*2, KEEP PERSON WARM/AT REST. CALL

RTECS: 9999999ZZ

IMMED. IF BRTHG HAS STOPPED, ARTF RESP SHLD BE GIVEN

RTECS: 9999999ZZ

RESPIRATORY PROTECTION BEFORE THE PERSON RETURNS TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 490 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: ACUTE: IRRIT TO NOSE, MOUTH,
THROAT & LUNGS, NAUS, HDACH OR DIZZ. CAUSE BURNS TO RESP TRACT
W/PRODN OF LUNG EDEMA WHICH CAN RSLT IN SHORTNESS OF BREATH,
WHEEZING, CHOKING, CHEST PAIN & IMPAIRME NT OF LUNG FUNCTION. INHAL
OF HIGH CONCCAN RSLT IN PERM LUNG DMG. CHRONIC: IMPAIRMENT OF LUNG
FUNCTION (EFT OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: & PERM LUNG DMG. EYE:SEV IRRIT &/OR
BURNS CAN OCCUR FOLLOWING EYE EXPOSURE. CONT MAY CAUSE IMPAIRMENT
OF VISION/CORNEAL DMG. SKIN:ACUTE: CAN CAUSE SEV IRRIT/BURNS
CHARACT BY REDNESS/SWELLING /SCAB FORMATION. PRLNG EXPOS MAY CAUSE
DESTRUCT OF DERMIS W/IMPAIRMENT OF SKIN AT SITE OF CONT TO
REGENERATE.(SUPP DATA)
Medical Cond Aggravated by Exposure:ASTHMA AND RESPIRATORY AND
CARDIOVASCULAR DISEASE.

First Aid:EYES: IMMED FLUSH W/LG AMTS OF H*2O FOR AT LST 15 MIN, OCCAS
LIFTING UPPER/LOWER EYELIDS. CALL MD IMMED. SKIN: IMMED FLUSH
W/H*2O FOR AT LST 15 MIN. CALL MD. REMOVE CONTAMD CLTHG IMMED &
WASH BEFORE R EUSE. INGEST: IMMED DRINK LG QTYS OF WATER. DO NOT
INDUCE VOMIT. CALL MD IMMED. DO NOT GIVE ANYTHING BY MOUTH TO UNCON
PERSON OR IF HAVING CONVL. INHAL: MOVE TO FRESH AIR. IF BRTHG IS
DFCLT, (ING 4)

Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . DO NOT
USE DRY CHEMICAL EXTINGUISHERS CONTAINING AMMONIA COMPOUNDS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. USE WATER TO COOL CONTRS EXPOSED TO FIRE. ON SML FIRES, USE WATER
SPRAY OR FOG. ON LG FIRES, (SUPP DATA)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:HAZ CONC IN AIR MAY BE FOUND IN LOCAL SPILL
AREA & IMMED DOWNWIND. IF SPILL IS DRY, DO NOT PUT WATER DIRECTLY
ON PROD AS GAS EVOLITON MAY OCCUR. IF WET, CONT OCEAN NETWORK FOR
PROPER STABILIZATION PRO C. VAPS MAY BE SUPRESSED BY WATER FOG.
(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT TAKE INTERNALLY. AVOID CONT
W/SKIN, EYES, CLTHG. STORE IN CLEAN DRY WELL VENTD AREA. KEEP AWAY
FROM INCOMPAT CHEM. DO NOT STORE >60C (>140F).
Other Precautions:OXIDIZER, SKIN CORROSIVE, EYE HAZARD, ORAL TOXIN,
LUNG TOXIN. HARMFUL IF INHALED OR INGESTED. HGARMFUL IF EXPOSED TO
SKIN OR EYES.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR EQUIPPED
W/CHEMICAL CARTRIDGE FOR PROTECTION AGAINST CHLORINE GAS AND A
DUST/MIST TYPE PREFILTER.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST LEVELS.
Protective Gloves:NEOPRENE/CHLORINATED POLYETHYLENE(ING 9)
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:NEOPRENE/CHLORINATED POLYETHYLENE/BUTYL
RUBBER AND SARANEX TYPE BOOTS/APRONS OR IMPERMEABLE SUIT TO AVOID
SKIN/EYE CONT.
Work Hygienic Practices:UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH
WATER.
Supplemental Safety and Health
PH OF 1% SOLN: 2.7-2.9. FIRE FIGHT PROC: USE HEAVY DELUGE/FOG STREAMS.
FLOODING AMTS OF WATER MAY BE REQD BEFORE EXTINGUISHMENT CAN BE
ACCOMPLISHED. EFTS OF OVEREXP: CHRONIC: EFTS SECONDARY TO TISS DE
STRUCT. INGEST: IRRIT/BURNS CAN OCCUR TO GI TRACT, INCL
STOM/INTESTINES, CHARACT BY NAUS/VOMIT/DIARR/ABDOM PAIN/ (ING 3)

HCC:D1
Decomp Temp:Decomp Text:437F,225C
Spec Gravity:>1 @ 20C
pH:SUPDAT
Solubility in Water:1.2% @ 25C
Appearance and Odor:WHITE GRANULAR SOLID OR TABLET-FORM PRODUCT. SHARP,
CHLORINE-LIKE, BLEACH ODOR.

Stability Indicator/Materials to Avoid:YES
ORGANIC MATLS, OILS, GREASE, SAWDUST, REDUCING AGENTS, NITROGEN CNTNG
CMPDS, OTHER OXIDIZERS, ACIDS, BASES.
Stability Condition to Avoid:AVOID TEMP >225C (>437F), CONT W/H*2O
WHICH MAY RSLT IN EXOTHERMIC RXN W/LIBERATION OF TOX FUMES,
SLIGHTLY WET PROD.
Hazardous Decomposition Products:NITROGEN TRICHLORIDE, CHLORINE,
NITROUS OXIDES, CYANATES, CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:NEUT FOR DISP; YOU ARE REQUESTED TO CONT OCEAN
AT 800-OLIN-911 BEFORE BEGINNING ANY SUCH OPERATION. AS HAZ SOLID
WASTE, IT MUST BE DISPOSED OF I/A/W LOCAL, STATE, & FEDERAL REGS IN
PERMITTED HAZ WASTE TREATMENT/STORAGE/DISPOSAL FACILITY BY(ING 8)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.